by E. Punzón-Quijorna, V. Torres-Costa, M. Manso-Silván, R. J. Martín-Palma and A. Climent-Font
Abstract:
Porous silicon (PS), in the form of single layer and multilayer structures, is a low-cost nanomaterial with applications in a wide range of fields. Hence, there is an increasing interest on the fabrication of laterally patterned PS structures. In biophysics for example, PS is a promising material for the development of low cost optical biochips, due to its remarkable biocompatibility and adjustable surface chemistry and optical properties. However, conventional lithography processes have shown to be not suitable for the proper patterning of PS. In this work, implantation of MeV Si ions is proposed as an effective tool for the localized formation of PS in the micrometer range. As previously reported by other groups, irradiation of silicon with H and He keV ions can inhibit the formation of PS. In the case of heavier ions, its higher damage efficiency allows for lower implantation doses to achieve PS growth inhibition, which allows shorter process times, and at the same time provides good lateral resolution below the micrometric range. Besides, the usage of ions of the same elementary nature as the target material avoids inconvenient side effects that may be ascribed to the implanted species. Two dimensional PS patterns with feature size of few micrometers have been successfully fabricated. Fluorescence and scanning electron microscopy reveal the proper transfer of different mask motifs into a PS/silicon patterned structure. Patterns present well defined lateral contrast and flat surface with no significant height variations, mandatory features for the development of PS based biochips. A resistivity increase has been observed on irradiated samples which could explain the inhibition of PS formation. This effect is attributed to dopant deactivation by the ion beam, since backscattering channeling measurements show no significant lattice damage.
Reference:
E. Punzón-Quijorna, V. Torres-Costa, M. Manso-Silván, R. J. Martín-Palma and A. Climent-Font, “MeV Si ion beam implantation as an effective patterning tool for the localized formation of porous silicon”, Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, vol. 282, no. Supplement C, pp. 25–28.
Bibtex Entry:
@article{punzon-quijorna_mev_2012,
	series = {Ion {Beam} {Synthesis} and {Modification} of {Nanostructured} {Materials} and {Surfaces}},
	title = {{MeV} {Si} ion beam implantation as an effective patterning tool for the localized formation of porous silicon},
	volume = {282},
	issn = {0168-583X},
	url = {http://www.sciencedirect.com/science/article/pii/S0168583X11008317},
	doi = {10.1016/j.nimb.2011.08.040},
	abstract = {Porous silicon (PS), in the form of single layer and multilayer structures, is a low-cost nanomaterial with applications in a wide range of fields. Hence, there is an increasing interest on the fabrication of laterally patterned PS structures. In biophysics for example, PS is a promising material for the development of low cost optical biochips, due to its remarkable biocompatibility and adjustable surface chemistry and optical properties. However, conventional lithography processes have shown to be not suitable for the proper patterning of PS. In this work, implantation of MeV Si ions is proposed as an effective tool for the localized formation of PS in the micrometer range. As previously reported by other groups, irradiation of silicon with H and He keV ions can inhibit the formation of PS. In the case of heavier ions, its higher damage efficiency allows for lower implantation doses to achieve PS growth inhibition, which allows shorter process times, and at the same time provides good lateral resolution below the micrometric range. Besides, the usage of ions of the same elementary nature as the target material avoids inconvenient side effects that may be ascribed to the implanted species. Two dimensional PS patterns with feature size of few micrometers have been successfully fabricated. Fluorescence and scanning electron microscopy reveal the proper transfer of different mask motifs into a PS/silicon patterned structure. Patterns present well defined lateral contrast and flat surface with no significant height variations, mandatory features for the development of PS based biochips. A resistivity increase has been observed on irradiated samples which could explain the inhibition of PS formation. This effect is attributed to dopant deactivation by the ion beam, since backscattering channeling measurements show no significant lattice damage.},
	number = {Supplement C},
	urldate = {2017-10-10},
	journal = {Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms},
	author = {Punzón-Quijorna, E. and Torres-Costa, V. and Manso-Silván, M. and Martín-Palma, R. J. and Climent-Font, A.},
	month = jul,
	year = {2012},
	keywords = {Porous silicon, Ion beam modification, Patterned porous silicon, Surface functionalization},
	pages = {25--28},
	file = {ScienceDirect Full Text PDF:E:\cmam_papers\files\1221\Punzón-Quijorna et al. - 2012 - MeV Si ion beam implantation as an effective patte.pdf:application/pdf;ScienceDirect Full Text PDF:E:\Usuarios\Administrator\Zotero\storage\J8G537IA\Punzón-Quijorna et al. - 2012 - MeV Si ion beam implantation as an effective patte.pdf:application/pdf;ScienceDirect Snapshot:E:\cmam_papers\files\1220\S0168583X11008317.html:text/html;ScienceDirect Snapshot:E:\Usuarios\Administrator\Zotero\storage\RHKNGKL5\S0168583X11008317.html:text/html},
}