by Trinitat Pradell, Radostin S. Pavlov, Patricia Carolina Gutiérrez, Aurelio Climent-Font and Judit Molera
Abstract:
Lusters are composite thin layers of coinage metal nanoparticles in glass displaying peculiar optical properties and obtained by a process involving ionic exchange, diffusion, and crystallization. In particular, the origin of the high reflectance (golden-shine) shown by those layers has been subject of some discussion. It has been attributed to either the presence of larger particles, thinner multiple layers or higher volume fraction of nanoparticles. The object of this paper is to clarify this for which a set of laboratory designed lusters are analysed by Rutherford backscattering spectroscopy, transmission electron microscopy, x-ray diffraction, and ultraviolet-visible spectroscopy. Model calculations and numerical simulations using the finite difference time domain method were also performed to evaluate the optical properties. Finally, the correlation between synthesis conditions, nanostructure, and optical properties is obtained for these materials.
Reference:
Trinitat Pradell, Radostin S. Pavlov, Patricia Carolina Gutiérrez, Aurelio Climent-Font and Judit Molera, “Composition, nanostructure, and optical properties of silver and silver-copper lusters”, Journal of Applied Physics, vol. 112, no. 5, pp. 054307.
Bibtex Entry:
@article{pradell_composition_2012,
	title = {Composition, nanostructure, and optical properties of silver and silver-copper lusters},
	volume = {112},
	issn = {0021-8979},
	url = {http://aip.scitation.org/doi/10.1063/1.4749790},
	doi = {10.1063/1.4749790},
	abstract = {Lusters are composite thin layers of coinage metal nanoparticles in glass displaying peculiar optical properties and obtained by a process involving ionic exchange, diffusion, and crystallization. In particular, the origin of the high reflectance (golden-shine) shown by those layers has been subject of some discussion. It has been attributed to either the presence of larger particles, thinner multiple layers or higher volume fraction of nanoparticles. The object of this paper is to clarify this for which a set of laboratory designed lusters are analysed by Rutherford backscattering spectroscopy, transmission electron microscopy, x-ray diffraction, and ultraviolet-visible spectroscopy. Model calculations and numerical simulations using the finite difference time domain method were also performed to evaluate the optical properties. Finally, the correlation between synthesis conditions, nanostructure, and optical properties is obtained for these materials.},
	number = {5},
	urldate = {2017-10-10},
	journal = {Journal of Applied Physics},
	author = {Pradell, Trinitat and Pavlov, Radostin S. and Carolina Gutiérrez, Patricia and Climent-Font, Aurelio and Molera, Judit},
	month = sep,
	year = {2012},
	pages = {054307},
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}